• Platinum-Rare Earth Alloy Electrocatalysts for the Oxygen Reduction Reaction: A Brief Overview, Carlos A. Campos-Roldán, Deborah J. Jones, Jacques Rozière, and Sara Cavaliere, ChemCatChem 2022, e202200334 - DOI: - OPEN ACCESS - PDF

The development of highly active and long-term stable electrocatalysts for the cathode of proton-exchange membrane fuel cells (PEMFC) is a paramount requirement for high performance and durable PEMFC stacks. In this regard, alloying Pt with rare earth metals (REM) has emerged as a promising approach. This short review summarizes and discusses the most relevant advances on Pt- REM alloy electrocatalysts, from bulk polycrystalline surfaces to carbon supported nanostructures, for the oxygen reduction reaction (ORR), and their implementation in PEMFCs, and is a starting point to establish the challenges in synthesis and design and properties goals for novel Pt-REM alloys.

    • Nitrogen Plasma Modified Carbons for PEMFC with Increased Interaction with Catalyst and IonomerA. Parnière, P.-Y. Blanchard, S. Cavaliere, N. Donzel, B. Prelot, J. Rozière and D. J. Jones, 2022 J. Electrochem. Soc. 169 044502 - DOI: - OPEN ACCESS - PDF

Vulcan XC72 carbon black, conventionally used as electrocatalyst support in proton exchange membrane fuel cells, was doped with nitrogen functionalities by exposing it to nitrogen plasma, and the effect on its morphology, structure and texture and surface properties was investigated. In particular, the strength of the interaction between the modified carbon and Nafion® ionomer was evaluated by isothermal titration calorimetry, and an enhanced exothermic effect was observed on increasing the amount of nitrogen at the Vulcan surface. The undoped and nitrogen-doped carbon blacks were catalysed with Pt nanoparticles, and the resulting materials were characterised for their electrocatalytic properties towards the oxygen reduction reaction. The electrocatalyst using nitrogen-doped supports are characterised by higher activity and stability, which is attributed to a strong Pt-support interaction promoted by the presence of the heteroatoms.

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